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DC Field | Value | Language |
---|---|---|
dc.rights.license | http://creativecommons.org/licenses/by-nc-nd/4.0 | es_MX |
dc.creator | DAVID MORALES_MORALES | - |
dc.date.accessioned | 2020-03-02T15:31:21Z | - |
dc.date.available | 2020-03-02T15:31:21Z | - |
dc.date.issued | 2020 | - |
dc.identifier.uri | http://rdu.iquimica.unam.mx/handle/20.500.12214/1228 | - |
dc.description.abstract | The synthesis, characterization and catalytic evaluation of a series of NHC-Ni(II) complexes1-Ni(-Me),2-Ni(-nBu) and3-Ni(-Bn) bearing a phthalimide fragment and a cyclopentadienyl (Cp) ligand is reported.The complexes were evaluated in CAS couplings of iodobenzene and a range of thiols. The reactions werecarried out using a catalyst loading of 5 mol % in DMF during 0.5–19 h. Being complex2-Nithe oneexhibiting the best activity for these transformations yielding up to 96% of products in 0.5 h | es_MX |
dc.language.iso | eng | es_MX |
dc.relation.uri | www.elsevier.com/locate/jcat | es_MX |
dc.rights | info:eu-repo/semantics/closedAccess | es_MX |
dc.source | Journal of Catalysis (ISSN 0021-9517) 383, 193-198 | es_MX |
dc.title | C[sbnd]S cross-coupling catalyzed by a series of easily accessible, well defined Ni(II) complexes of the type [(NHC)Ni(Cp)(Br)] | es_MX |
dc.type | info:eu-repo/semantics/article | es_MX |
dc.creator.id | info:eu-repo/dai/mx/orcid/0000-0002-7984-1819 | es_MX |
dc.subject.cti | info:eu-repo/classification/cti/2 | es_MX |
dc.subject.keywords | C-S cross-coupling | es_MX |
dc.subject.keywords | Thioetherification reaction | es_MX |
dc.subject.keywords | NHC complexes | es_MX |
dc.subject.keywords | Nickel complexes | es_MX |
dc.subject.keywords | Thiolation reaction | es_MX |
dc.subject.keywords | Catalysis | es_MX |
dc.type.uri | https://doi.org/10.1016/j.jcat.2020.01.016 | es_MX |
dc.creator.two | Simon Hernandez-Ortega | - |
dc.creator.three | Hugo Valdés | - |
dc.creator.four | Ernesto Rufino-Felipe | - |
dc.creator.idtwo | info:eu-repo/dai/mx/orcid/0000-0002-1034-5673 | es_MX |
dc.creator.idthree | info:eu-repo/dai/mx/orcid/0000-0001-8815-0019 | es_MX |
dc.creator.idfour | info:eu-repo/dai/mx/orcid/0000-0003-1619-6602 | es_MX |
Appears in Collections: | Artículos |
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